刘煜 教授

   发布时间: 2023-10-15    访问次数: 3304

刘煜，男，汉族，湖南邵阳人，博士，教授，博士生导师，中国化学会会员，湘潭市第十一届政协委员，湖南省新世纪121人才工程第三层次人选, 湖南省高等学校青年骨干教师，湖南省教育厅优秀青年基金获得者，湖南省《有机化学实验》精品课主讲教师。国际学术期刊Macromolecules; Poly. Chem.; ACS Appl. Mater. Interfaces; Inorg. Chem.; Org. Electron.; RSC. Adv.; J. Chem.; Med. Chem.; New J. Chem.等刊物特邀审稿人。主要从事有机电致发光材料及其聚合物发光器件、有机/聚合物太阳能电池材料与器件等国际前沿科学领域的研究。2017年6月加盟常州大学材料科学与工程学院。

自08年来，先后主持国家和省部级项目10余项：国家自然科学基金面上项目3项，教育部博士点新教师基金1项、湖南省教育厅重点项目1项，湖南省自然科学基金2项和湖南省教育厅青年基金1项等；作为主要研究人员参与国家自然科学基金面上项目2项合省部级项目5项。指导湖南省大学生研究性学习和创新性实验计划项目1项。分别获得湖南省自然科学二等奖1项（2010，排名第4）和第十届湖南省高等教育省级教学成果二等奖（2013，排名第5）；以第一和通信联系人先后在Poly. Chem., J. Mater. Chem. C, J. Phys. Chem. C, Org. Electron., Dalton Trans.等国内外重要学术刊物上发表学术论文50余篇，国际、国内学术会议论文30余篇，申请6项国家发明专利，获授权国家发明专利3 项。

【学习经历】

1991.09 ~ 1995.06理学学士，化学专业，南开大学大学化学系

1998.09 ~ 2001.09硕士学位，有机化学，四川大学化学学院

2003.09 ~ 2007.06理学博士，高分子化学与物理，湘潭大学化学学院

【工作经历】

1995.07 ~ 1998.09

助理讲师，琼州大学化学系

2001.09 ~ 2003.09

讲师，琼州大学化学系

2007.06 ~ 2008.10

讲师，湘潭大学化学学院，湖南省普通高校青年骨干教师培养对象，有机教研室主任

2008.10 ~ 2012.08

副教授/硕士生导师，湖南省新世纪“121”人才，湘潭大学化学学院，有机教研室主任

2012.09 ~ 2013.11

副教授/破格为博士生导师，湘潭大学化学学院

2013.12 ~2017.06

教授/博士生导师，湘潭大学化学学院

2017.07~

教授/博士生导师，常州大学材料科学与工程学院

【主要研究方向】

（1）有机/聚合物光电功能材料及其分子器件

【主要学术成果】

一、近5年以来发表的主要学术论文（第一通讯联系人）

  1. 1.KaiZhang, Yajun Liu, Qiang Zhang, Tianyu Wang*, Suqian Cui, Weiguo Zhu*, and Yu Liu*, An effective strategy to obtain near-infrared emission from shoulder to shoulder-type binuclear platinum(II) complex based on fused pyrene core bridged isoquinoline ligands, Journal of Materials Chemistry C, 2021, 9, 2282-2290.

  2. 2.Liang Zeng, Ruijie Ma, Qiang Zhang, Tao Liu,* Yiqun Xiao, Kai Zhang, Suqing Cui, Weiguo Zhu, Xinhui Lu, He Yan,* Yu Liu*, Synergy Strategy to the Flexible Alkyl and Chloride Side-chain Engineered Quinoxaline-Based D-A Conjugated Polymers for Efficient Non-fullerene Polymer Solar Cells, Materials Chemistry Frontiers, 2021, 5, 1906-1916.

  3. 3.Suqian Cui, Liang Zeng, Zhongxin Zhou, Gangtie Lei*, Yongchuan Xu, Weiguo Zhu*, Yu Liu*, Fluorine substituted asymmetric planar aromatic backbone indo[2,3-b]quinoxaline unit based on narrow bandgap copolymer for fullerene polymer solar cells, Organic Electronics, 2021, 95, 106194.

  4. 4.Qiang Zhang, Chengjia Bao, Suqian Cui, Ping Zhong,* Kai Zhang, Weiguo Zhu* and Yu Liu*，Boosting the efficiency of PTB7-Th:PC71BM polymer solar cells via a low-cost halogen-free supramolecular solid additive, Journal of Materials Chemistry C, 2020, 8, 16551-16560.

  5. 5. Zhaoran Hao, Kai Zhang, Pu Wang, Xumin Lu, Zhiyun Lu, Weiguo Zhu, Yu Liu*, Deep Red Iridium(III) Complexes Based on Pyrene-substituted Quinoxaline Ligands for Solution-Processed Phosphorescent Organic Light-Emitting Diodes, Inorganic Chemistry, 2020, 59，332-342.

  6. 6. Zhaoran Hao, Kai Zhang, Kuan Chen, Pu Wang, Zhiyun Lu,* Weiguo Zhu* and Yu Liu*. More Efficient Spin-Orbit Coupling:Adjusting Ligand Field Strength to the Second Metal Ion in Asymmetric Binuclear Platinum(II) Configurations, Dalton Transactions, 2020, 49, 8722-8733.

  7. 7. Zhen Yang, Chengjia Baoa, Guangjun Zhang, Zuoji Liu, Weiguo Zhu*, Suqian Cui, Qiang Peng,* Yu Liu,* Low-cost donors based on a dicarboxylic ester side-chain substituted thieno [3,2-b]thiophene unit for efficient polymer solar cells，Dyes and Pigments,2020, 182, 108698.

  8. 8. Kai Zhang, Yajun Liu, Zhaoran Hao, Gangtie Lei*, Suqian Cui, Weiguo Zhu*, Yu Liu*, feasible approach to obtain near-infrared (NIR) emission from binuclear platinum(II) complexes containing centrosymmetric isoquinoline ligand in PLEDs, Organic Electronics, 2020, 87, 105902.

  9. 9.Zuoji Liu, Chengjia Bao, Guangjun Zhang, Kai Zhang, Gangtie Lei*, Qiang Zhang, Qiang Peng*, Yu Liu*, Enhancement the photovoltaic performance of conjugated polymer based on simple head-to-head alkylthio side chains engineered bithiophene, Chinese Chemical Letters, 2020, 31，2459-2464.

  10. 10. Zuoji Liu, Chengjia Bao, Xiaopeng Xu, Gangtie Lei*, Huishan Gao, Qiang Peng*, Yu Liu*, Tuning terminal units to improve the photovoltaic performance of small molecules based on a large planar fused-ring core in solution-processed organic solar cells, Organic Electronics, 2020, 78, 105566.

  11. 11.Zhaoran Hao, Kai Zhang, Kuan Chen, Zhiyun Lu, Pu Wang,Weiguo Zhu and Yu Liu*, An Effective Approach to Obtain Near-infrared Emission From Binuclear Platinum(II) Complexes Involving Thiophenpyrdine-isoquinoline Bridging Ligand in Solution Processed OLEDs, Chemistry-An Asian Journal, 2020, 15, 3003–3012.

  12. 12.Min Li, Shichao Wang, Chengjia Bao, Zuoji Liu, Dan Bai, Zhen Yang,b Weiguo Zhu, Qiang Peng, Yu Liu*, Improving the Photovoltaic Performance of Fluorinated 2,2'-Bithiophene Core-Based D(A-Ar)2 Type Small Molecules via Strategically End-capped Heteroaromatic Substitution, Journal of Materials Chemistry C,2019, 7, 12217—12230.

  13. 13.Min Li, Zuojia Li, Zhen Yang, Zuoji Liu, Weiguo Zhu, Chengjia Bao, Liang Yang, Qiang Peng*, Yu Liu*, An effective heteroatom-substituted strategy on Photovoltaic Properties of  D(A-Ar)2 Small Molecules for Efficient Organic Solar Cells,Dyes and Pigments,2019, 170, 107595.

  14. 14. Min Li, Zhongbin Qiu, Guangjun Zhang, Yu Liu,* Lin Xiong, Dan Bai*, Mengbing Zhu,b Qiang Peng and Weiguo Zhu, Efficient chemical structure and device engineering for achieving difluorinated 2,20-bithiophene-based small molecular organic solar cells with 9.0% efficiency, Journal of Materials Chemistry A, 2018, 6, 12493–12505.

  15. 15. Min Li, Guangjun Zhang, Lin Xiong, Mengbing Zhu, Yong Pei,∗, Qiang Peng,∗,Yu Liu∗, Adjusted photovoltaic performance of tetrafluorobenzene-based small molecules by tailoring with different arm of acceptor units,Dyes and Pigments, 2018, 158, 402-411.

  16.  16.Zhongbin Qiu, Xiaopeng Xu, Liang Yang, Yong Pei, Mengbin Zhu, Qiang Peng, Yu Liu*,Tuning the Central Donor Core via Intramolecular Noncovalent Interactions Based on D(A-Ar)2 Type Small Molecules for High Performance Organic Solar cells, Solar Energy,  2018, 161,138-147.

  17.  17.Hao, Min Li, Yajun Liu, Yafei Wang, Guohua Xie, Yu Liu*，Near-infrared emission of dinuclear iridium complexes with hole/electron transporting bridging and their monomer in solution processed organic light-emitting diodes，Dyes and Pigments, 2018, 149, 315-312.

  18. 18.Yu Liu*, Zhaoran Hao, Haigang Jiang, Yajun Liu, Yafei Wang, Hua Tan, Guohua Xie*, High-efficiency blue OLEDs based on dendritic dinuclear iridium (III) complexes grafted with fluorene core and blue fluorescence chromospheres, Tetrahedron, 2018, 74, 425-432.

  19. 19.Yu Liu*, Zhaoran Hao, Fanyuan Meng, Pu Wang, Liang Yang, Yafei Wang, Yong Pei*, Shijian Su*, Efficient near-infrared emission of p-extended cyclometalated iridium complexes based on pyrene in solution-processed polymer lightemitting diode,Chemical Physics Letters, 2018, 699, 99–106.

  20. 20. Zhaoran Hao, Fanyuan Meng, Pu Wang, Yafei Wang, Hua Tan, Yong Pei, Shijian Su, Yu Liu*，Dual phosphorescence emission of dinuclear platinum(II) complex incorporating cyclometallating pyrenyl-dipyridine-based ligand and its application in near-infrared solution-processed polymer light-emitting diodes，Dalton Transactions，2017, 46, 16257-16268.

  21. 21. Zhongbin Qiu, Xiaopeng Xu, Shuai Zhang, Pu Wang, Yafei Wang, Yong Pei, Qiang Peng, Yu Liu*, Efficient strategies to improve photovoltaic performance of A-D-A type small molecules by introducing rigidly fluorinated central cores,Dyes and Pigments, 2017, 147, 505-513.

  22.  22.Zhaoran Hao, Yu Liu*, Ying Huang, Fanyuan Meng, Yafei Wang, Hua tan, Shijian Su*, Weiguo Zhu*，Synthesis and optoelectronic properties of dinuclear cyclometalated platinum (II) complexes containing naphthalene-functionalized carbazole groups in the single- emissive-layer WPLEDs, Journal of Organometallic Chemistry, 2017, 835, 52-59.

  23. 23. Zhaoran Hao, Haigang Jiang, Yu Liu*, Youming Zhang, Junting Yu, Yafei Wang, Hua Tan, Shijian Su*, Weiguo Zhu*, Synthesis and optoelectronic properties of dinuclear iridium (III) complexes containing deep blue fluorescence chromophore in the single-emissive-layer WPLEDs, Tetrahedron,2016, 72, 8542-8549.

  24.  24.Youming Zhang, Haigang Jiang, Yu Liu*, Kaifeng Zhou, Yafei Wang, Hua Tan, Shijian Su, Weiguo Zhu a*，Dinuclear Cyclometalated Platinum(II) Complexes Containing Deep Blue Fluorescence Chromophore: Synthesis, Photophysics and Application in Single Dopant White PLEDs, Dalton Trans.2016, 45, 14131-14140.

  25.  25.Qunping Fan, Xiaopeng Xu, Yu Liu*, Wenyan Su, Xunming He, Youming Zhang, Hua Tan, Yafei Wang, Qiang Peng*, Weiguo Zhu*, Enhancing photovoltaic properties of low bandgap terpolymers based on benzodithiophene and phenanthrophenazine by introducing different second acceptor units, Polymer Chemistry,2016, 7, 1747–1755 |.  

  26. 26. Qunping Fan, Huanxiang Jiang, Yu Liu*, Wenyan Su, Hua Tan, Yafei Wang, Renqiang Yang*, Weiguo Zhu*，Efficient polymer solar cells based on a new quinoxaline derivative with fluorinated phenyl side chain，Journal of Materials Chemistry C, 2016, 2016, 4, 2606—2613.

  27. 27. Qunping Fan, Yu Liu*, Huanxiang Jiang, Linrui Duan, Hua Tang, Yuanyuan Li, Jiyong Deng, Renqiang Yang*, Weiguo Zhu*, Fluorination as an effective tool to increase the photovoltaic performance of indacenodithiophene-alt-quinoxaline based wide-bandgap copolymers, Organic Electronics, 2016, 33:128-134.

  28. 28. Delong Yu, Yu Liu*, Manjun Xiao, Qunping Fan, Wenyan Su, Xiao Li, Hua Tan, Yafei Wang, Renqiang Yang*, Weiguo Zhu*, Synthesis and photovoltaic performance of DPP-based small molecules with tunable energy levels by altering the molecular terminals, Dyes and Pigments, 2016, 125, 151-158.

  29.  29.Delong Yua, Yu Liu*, Qunping Fan, Manjun Xiaoa, Hua Tana, Yafei Wanga, Renqiang Yangb,*, Weiguo Zhua, Improved photovoltaic performance of D-A-D-type small molecules with isoindigo and pyrene units by inserting different π-conjugated bridge, Tetrahedron, 2016, 72，4543-4549.

  30.  30.Qunping Fan, Manjun Xiao, Yu Liu*, Wenyan Su, Huishan Gao, Hua Tan, Yafei Wang, Gangtie Lei, Renqiang Yang* and Weiguo Zhu*. Improved photovoltaic performance of a 2D-conjugated benzodithiophene-based polymer by the side chain engineering of quinoxaline. Polymer Chemistry, 2015, 6, 4290-4298.

  31. 31.Qunping Fan, Yu Liu*, Manjun Xiao, Wenyan Su, Huishan Gao, Jianhua Chen, Hua Tan, Yafei Wang, Renqiang Yang* and Weiguo Zhu*. Enhancing the photovoltaic properties of terpolymers containing benzo[1,2-b:4,5-b′]dithiophene, phenanthro[4,5-abc]phenazine and benzo[c][1,2,5]thiadiazole by changing the substituents. Journal of Materials Chemistry C, 2015, 3, 6240-6248.

  32.  32.Qunping Fan, Yu Liu*, Pingao Yang, Wenyan Su, Manjun Xiao, Jianhua Chen, Min Li, Xiangdong Wang, Yafei Wang, Hua Tan, Renqiang Yang*, Weiguo Zhu*. Benzodithiophene-based two-dimensional polymers with extended conjugated thienyltriphenylamine substituents for high-efficiency polymer solar cells.Organic Electronics, 2015, 23, 124–132.

  33.  33.Qunping Fan, Min Li, Pingao yang, Yu Liu*, Manjun Xiao, Xiangdong Wang, Hua Tan, Yafei Wang, Renqiang Yang*, Weiguo Zhu*. Acceptor-donor-acceptor small molecules containing benzo [1,2-b:4,5-b'] dithiophene and rhodanine units for solution processed organic solar cells. Dyes and Pigments, 2015, 116, 13-19.

  34.  34.Qunping Fan, Jiaojiao Cui, Yu Liu*, Wenyan Su, Yafei Wang, Hua Tan, Delong Yu, Huishan Gao, Xianping Deng, Weiguo Zhu*. Synthesis and photovoltaic properties of two star-shaped molecules involving henylquinoxaline as core and triphenylamine and thiophene units as arms. Synthetic Metals, 2015, 204, 25-31.

  35. 35. Qunping Fan, Yu Liu*, Zhaoran Hao, Chun Li, Yafei Wang, Hua Tan, Weiguo Zhu*, Yong Cao. Polymer light-emitting devices based on europium(III) complex with 11-bromo-dipyrido[3,2-a:2',3'-c]phenazine. Science China Chemistry, 2015, 58, 1152-1158.

  36. 36. Qunping Fan, Yu Liu*, Manjun Xiao, Hua Tan, Yafei Wang, Wenyan Su, Delong Yu, Ren- qiang Yang*, Weiguo Zhu*. Dono-acceptor copolymers based on benzo[1,2-b:4,5-b'] dithiophene and pyrene-fused phenazine for high-performance polymer solar cells. Organic Electronics, 2014, 15, 3375-3383.

  37. 37.Yu Liu, Yafei Wang, Chun Li, Ying Huang, Dongfeng Dang, Meixiang Zhu, Weiguo Zhu*, Yong Cao,* Red polymer light-emitting devices based on an oxadiazole functionalized europium(III) complex. Materials Chemistry and Physics. 2014, 143, 1265-1270.

  38. 38. Pingao Yang, Shan Chen, Yu Liu*,Zuo Xiao, Liming Din*.A pyridine-functionalized pyrazolinofullerene used as a buffer layer in polymer solar cells.Physical Chemistry Chemical Physics, 2013, 15, 17076-17078.

  39. 39.Yu Liu*, Kai Chen, Kongqiang Xing, Yafei Wang, Haigang Jiang, Xiangping Deng, Meixiang Zhu, Weiguo Zhu*, Conjugated and nonconjugated bipolar-transporting dinuclear europium (III) complexes involving triphenylamine and oxadiazole units: Synthesis, photophysical and electroluminescent properties, Tetrahedron, 2013, 69, 4679-4686.

  40. 40.Yu Liu, Jianyu Wang, Yafei Wang, Zhiyong Zhang, Meixiang Zhu, Gangtie Lei, Weiguo Zhu*, Bipolar-transporting dinuclear europium(III) complexes involving carbazole and oxadiazole units: Synthesis, photophysical and electroluminescent properties，Dyes and Pigments，2012, 95, 322-329.

  41. 41.Yu Liu, Yafei Wang, Juan He, Qingqing Mei, Kai Chen, Jiaojiao Cui, Chun Li, Meixiang Zhu, Junbiao Peng, Weiguo Zhu*, Yong Cao. High-efficiency red electroluminescence from europium complex containing a neutral dipyrido (3,2-a:2,3-c)phenazine ligand in PLEDs. Organic Electronics, 2012, 13, 1038-1043.

  42. 42.Yu Liu, Yafei Wang, Haipeng Guo, Meixiang Zhu, Chun Li, Junbiao Peng, Weiguo Zhu*, Yong Cao. Synthesis and optoelectronic characterization of a monochromic red-emitting europium (III) complex containing triphenylamine-functionalized phenanthroline. Journal of Physical Chemistry. C, 2011, 115 (10), 4209-4216.


       二 、专利

  1. 1.刘煜，李满园, 朱卫国, 王亚飞, 谭华，铱-铕异质多核金属配合物合成及其在聚合物电致白光器件中的应用，中国发明专利号ZL 2015 1 0799836.7, 授权时间 2018. 05. 08.

  2. 2.刘煜， 郝昭然, 朱卫国, 王亚飞, 谭华，一类含有D-A-A构型π共轭体系的不对称双核环金属铂(II)配合物近红外电致磷光材料的合成及应用.中国发明专利号：ZL 2016 1 0348480.X. 授权时间2019.1.11.

  3. 3.刘煜，高辉山，刘座吉，朱卫国；杨振，基于咔唑十一元稠环平面核的D(A-Ar)2型有机光电化合物及制备方法和应用，中国发明专利，ZL 2019 1 0284775.9. 授权时间2020.12.25.

  4. 4.刘煜，李敏, 朱卫国，刘座吉, 杨振，一类烷基/硫烷基氮杂芳环末端的D(A-Ar)2型共轭化合物及其制备方法与应用，中国发明专利：ZL 2019 1 0279190.8. 授权日期：2021.06.22.

三、主持科研项目

1.刘煜，国家自然科学基金面上项目：基于共轭大π平面稠环噻吩为核的线型和星型有机小分子光伏材料的合成及其光伏性能研究（51573154），2016.01~2019.12，76.0 万元（在研）。

2.刘煜，国家自然科学基金面上项目：基于聚集态可控发光的有机双核环金属配合物电致白光材料的构筑及其聚合物白光器件的性能研究（51273168），2013.01~2016.12，80.0万元（结题）。

3.刘煜，国家自然科学基金面上项目：双极传输稀土金属配合物近红外发光材料的构筑及其电致发光性能的研究（20872124），2009.01~2011.12，28.0万元（结题）。

4.刘煜，湖南省自然科学基金：基于环金属铂配合物近红外发光材料的构筑及其电致发光性能的研究（2015JJ2139），2015.06~2017.06，4.0万元（在研）。

5.刘煜，湖南省教育厅重点项目：基于稠环噻吩窄带隙共轭聚合物的合成、能级调控及其光伏性能研究（13A102），2013.01~2016.12，6.0万元 (结题)。

6.刘煜，湖南省自然科学基金面上项目：双核稀土金属铒配合物近红外发光材料的合成及其聚合物发光器件的性能研究（11JJ3061），2011.01~2013.12，4.0万元（结题）。

7.刘煜，湖南省高等学校科学研究项目（优秀青年项目）：双极传输异核稀土配合物白光发光材料的构筑及其光电性能研究（10B112），2010.01~ 2012.12，2.0万元，（结题）。

8.刘煜，高等学校博士学科点新教师基金项目：利用铕资源开发固态照明光源的研究（200805301013），2009.01~2012.12，3.6万元（结题）。

9.刘煜，湘潭大学博士启动费：新型稀土金属铕配合物的合成及其电致发光器件的性能研究（08QDZ29），2007.09~2009.12，8.0万元，（结题）。

10.刘煜，环境友好化学与应用教育部重点实验室-开放基金（湘潭大学）：新型有机铒配合物近红外发光材料的构筑及其光电性能的研究（09HJYH0611CY023），2009.01~2010.12，1.0万元，（结题）。


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